Spin Interactions and Multiplicity as a Tool for Reactivity Control
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Institute of Organic Chemistry and Biochemistry of the Czech Academy of Sciences
Praha
Přehled The multiplicity of excited states in organic photochemistry is governed by electron spin and its interactions. Excited molecules most commonly occur in singlet or triplet states; interconversion between them and the resultant reactivity are controlled by spin-selection rules and the magnitude of spin–spin interactions. In particular, spin–orbit and exchange interactions affect the... |
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